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Discrimination of Mobile Supramolecular Chirality, Imayoshi


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Автор: Imayoshi
Название:  Discrimination of Mobile Supramolecular Chirality
ISBN: 9789811674334
Издательство: Springer
Классификация:




ISBN-10: 9811674337
Обложка/Формат: Soft cover
Страницы: 87
Вес: 0.17 кг.
Дата издания: 04.12.2022
Серия: Springer Theses
Язык: English
Издание: 1st ed. 2022
Иллюстрации: 35 illustrations, color; 28 illustrations, black and white; xiv, 87 p. 63 illus., 35 illus. in color.
Размер: 235 x 155
Читательская аудитория: Professional & vocational
Основная тема: Chemistry
Подзаголовок: Acylative molecular transformations by organocatalysis
Ссылка на Издательство: Link
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Поставляется из: Германии
Описание: This book proposes a novel concept for molecular recognition. In the field of asymmetric synthesis approaching the mature science, asymmetric discrimination and catalytic synthesis of chiral supramolecules still stand as unsolved problems. The extreme difficulty in asymmetric synthesis of such supramolecules may result from the mobile nature of supramolecular chirality. Here the author shows the first highly enantioselective synthesis of mechanically chiral supramolecules. In the presence of a chiral organocatalyst, a mechanically planar chiral rotaxane was obtained with p erfect enantiopurity (>99% ee) with an excellent selectivity. The dynamic and flexible recognition mode enabled asymmetric synthesis of supramolecules with conformational flexibility and mobility. The recognition mode of the catalyst is a contrast to the traditional static and rigid recognition mode of the typical conventional catalysts. The concept of dynamic molecular recognition will be adopted as a novel concept in a wide range of fields beyond the field of organic chemistry, including material chemistry, biochemistry, and medicinal chemistry.
Дополнительное описание: Introduction.- Mechanistic Study of Organocatalytic Chemoselective Monoacylation of 1,5-Pentanediol.- Discrimination of Mobile Supramolecular Chirality: Kinetic Resolution of Topologically Chiral Racemic Rotaxanes by Organocatalysis.- Conclusion and Persp


Discrimination of Mobile Supramolecular Chirality: Acylative Molecular Transformations by Organocatalysis

Автор: Imayoshi Ayumi
Название: Discrimination of Mobile Supramolecular Chirality: Acylative Molecular Transformations by Organocatalysis
ISBN: 9811674302 ISBN-13(EAN): 9789811674303
Издательство: Springer
Рейтинг:
Цена: 158380.00 T
Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: This book proposes a novel concept for molecular recognition. In the field of asymmetric synthesis approaching the mature science, asymmetric discrimination and catalytic synthesis of chiral supramolecules still stand as unsolved problems. The extreme difficulty in asymmetric synthesis of such supramolecules may result from the mobile nature of supramolecular chirality. Here the author shows the first highly enantioselective synthesis of mechanically chiral supramolecules. In the presence of a chiral organocatalyst, a mechanically planar chiral rotaxane was obtained with p erfect enantiopurity (>99% ee) with an excellent selectivity. The dynamic and flexible recognition mode enabled asymmetric synthesis of supramolecules with conformational flexibility and mobility. The recognition mode of the catalyst is a contrast to the traditional static and rigid recognition mode of the typical conventional catalysts. The concept of dynamic molecular recognition will be adopted as a novel concept in a wide range of fields beyond the field of organic chemistry, including material chemistry, biochemistry, and medicinal chemistry.

Fundamentals Of Supramolecular Chirality

Автор: Alessandro D`urso, Maria Elena Fragala, Roberto Purrello
Название: Fundamentals Of Supramolecular Chirality
ISBN: 1800610246 ISBN-13(EAN): 9781800610248
Издательство: World Scientific Publishing
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Цена: 95040.00 T
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Описание:

Fundamentals of Supramolecular Chirality is a critical description of the start and advancement of supramolecular chirality. This book focuses on the noncovalent approach with some supplementary examples of covalent supramolecular chirality.


This contribution to supramolecular chirality is not intended to be a mere catalogue and description of the work done. It also traces a philosophical path following the development and possible perspectives of this topic, providing not a review but a critical examination of the field.


Dendrimer Chemistry: Synthetic Approaches Towards Complex Architectures

Автор: Malkoch Michael, Garcia Gallego Sandra
Название: Dendrimer Chemistry: Synthetic Approaches Towards Complex Architectures
ISBN: 1788011325 ISBN-13(EAN): 9781788011327
Издательство: Royal Society of Chemistry
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Цена: 237950.00 T
Наличие на складе: Нет в наличии.
Описание: An overview of the latest advances in the synthesis, characterization and applications of dendrimers and other complex dendritic architectures.

Supramolecular Catalysts - Design, Fabrication, And Applications

Автор: Wang Leyong, Su Cheng-yong
Название: Supramolecular Catalysts - Design, Fabrication, And Applications
ISBN: 9811217793 ISBN-13(EAN): 9789811217791
Издательство: World Scientific Publishing
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Цена: 174240.00 T
Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: This book is indexed in Chemical Abstracts Service

Electronic and Magnetic Properties of Chiral Molecules and Supramolecular Architectures

Автор: Ron Naaman; David N Beratan; David Waldeck
Название: Electronic and Magnetic Properties of Chiral Molecules and Supramolecular Architectures
ISBN: 3642266983 ISBN-13(EAN): 9783642266980
Издательство: Springer
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Цена: 371750.00 T
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Описание: Time-dependent density functional response theory for electronic chiroptical properties of chiral molecules; by Yunjie Xu *Magneto-electric properties of self-assembled monolayers of chiral molecules; by Zeev Vager and Ron Naaman*Theory of adsorption induced chirality and electron transfer through chiral systems;

NMR in Supramolecular Chemistry

Автор: M. Pons
Название: NMR in Supramolecular Chemistry
ISBN: 9401059500 ISBN-13(EAN): 9789401059503
Издательство: Springer
Рейтинг:
Цена: 186330.00 T
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Описание: Proceedings of the NATO Advanced Research Workshop on Applications of NMR to the Study of Structure and Dynamics of Supramolecular Complexes, Sitges, Spain, 5-9 May 1998

Supramolecular Structure and Function 7

Автор: Greta Pifat-Mrzljak
Название: Supramolecular Structure and Function 7
ISBN: 1461355176 ISBN-13(EAN): 9781461355175
Издательство: Springer
Рейтинг:
Цена: 93160.00 T
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Описание: This volume represents a collection of lectures delivered by outstanding specialists in the fields of biophysics and of related scientific disciplines th during the 7 International Summer School on Biophysics held in Rovinj, Croatia from 14 to 25 September 2000 under the title "Super molecular Structure and Function ".

Advanced Macromolecular and Supramolecular Materials and Processes

Автор: Kurt E. Geckeler
Название: Advanced Macromolecular and Supramolecular Materials and Processes
ISBN: 1461346304 ISBN-13(EAN): 9781461346302
Издательство: Springer
Рейтинг:
Цена: 139750.00 T
Наличие на складе: Есть у поставщика Поставка под заказ.

Supramolecular Science

Автор: Rocco Ungaro; Enrico Dalcanale
Название: Supramolecular Science
ISBN: 9401059330 ISBN-13(EAN): 9789401059336
Издательство: Springer
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Цена: 139750.00 T
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Описание: A summary of all the most important aspects of supramolecular science, from molecular recognition in chemical and biological systems to supramolecular devices, materials and catalysis. The 17 chapters cover calixarenes, catenanes, cavitands, cholophanes, dendrimers, membranes and self-assembly systems, molecular modelling, molecular level devices, organic materials, peptides and protein surfaces, recognition of carbohydrates, rotaxanes, supramolecular catalysis. A forward-looking chapter written by J.-M. Lehn indicated the future prospects for the entire field.
Audience: Ph.D. students and young researchers in chemistry, physics and biology.

Supramolecular Structure and Function

Автор: Greta Pifat
Название: Supramolecular Structure and Function
ISBN: 1468444808 ISBN-13(EAN): 9781468444803
Издательство: Springer
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Цена: 46570.00 T
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Описание: The topics discussed at the school were inter- and intramolecular interactions in biological systems, and structure, organization and function of biological macromole- cules and supramolecular structures.

Physical Supramolecular Chemistry

Автор: L. Echegoyen; A.E. Kaifer
Название: Physical Supramolecular Chemistry
ISBN: 9401066280 ISBN-13(EAN): 9789401066280
Издательство: Springer
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Цена: 121110.00 T
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Описание: Proceedings of the NATO Advanced Research Workshop, Miami, U.S.A., January 7-10, 1996

Transition Metals in Supramolecular Chemistry

Автор: L. Fabbrizzi; Antonio Poggi
Название: Transition Metals in Supramolecular Chemistry
ISBN: 9048144833 ISBN-13(EAN): 9789048144839
Издательство: Springer
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Цена: 309330.00 T
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Описание: Proceedings of the NATO Advanced Research Workshop, Santa Margherita Ligure (Genoa), Italy, April 14--16, 1994


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