The Everyday Blacksmith: Learn to Forge 55 Simple Projects You`ll Use Every Day, with Multiple Variations for Styles and Finishes, Wicks Nicholas

Автор: Welford Mark, Wicks Stephen
Название: Simple Flower Arranging
ISBN: 1465415882 ISBN-13(EAN): 9781465415882
Издательство: Random House (USA)
Цена: 15940.00 T
Наличие на складе: Невозможна поставка.
Описание: From simple arrangements that brighten up a room, to one-of-a-kind gifts and gorgeous wedding bouquets, Simple Flower Arranging contains more than 60 inspirational projects that anyone can do at home.Learn key techniques such as hand-tying and using florist foam, as well as how to experiment with vintage tins, glassware, strings, and ribbons.The sumptuous photography and step-by-step sequences simply explain how to arrange like a professional.

Автор: Wicks Joe
Название: Lean in 15
ISBN: 1509800662 ISBN-13(EAN): 9781509800667
Издательство: Pan Macmillan
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Цена: 15400.00 T
Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: The first book from Instagram sensation Joe Wicks, aka The Body Coach.

Автор: Matthew Wicks
Название: Imaginative Projects Book
ISBN: 0521668050 ISBN-13(EAN): 9780521668057
Издательство: Cambridge University Press
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Цена: 17250.00 T
Наличие на складе: Нет в наличии.
Описание: Imaginative Projects is a photocopiable supplementary resource book for teachers of EFL learners aged 11-17. This book provides a bank of ten projects, on themes designed to capture the imagination of students and encourage them to use English naturally in groups to work on the project’s end product such as a poster, radio programme, or performance. This flexible material is linked to coursebook topics and language areas. Eight of the projects consist of four single lesson 'mini projects' that can be used independently. It offers step-by-step teaching notes, a cross-referenced map of the book and a mini-map at the start each project. If you need a motivating, enjoyable alternative to supplement your coursebook, this is the book for you.

Автор: Wicks, Robert
Название: Adventure motorcycling
ISBN: 1844254356 ISBN-13(EAN): 9781844254354
Издательство: Неизвестно
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Цена: 17590.00 T
Наличие на складе: Невозможна поставка.
Описание: Useful for adventure motorcycling, this book covers several aspect of the trip, including practicalities (cost, personal fitness, how long you can be away from home), choosing the right bike, equipment, clothing, legal documentation, riding techniques, maintenance, navigation and emergencies.

Автор: Wicks Joe
Название: Lean in 15: The Sustain Plan
ISBN: 1509820221 ISBN-13(EAN): 9781509820221
Издательство: Pan Macmillan
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Цена: 13080.00 T
Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: The third book in the Lean in 15 series by record-breaking bestselling author Joe Wicks.

Автор: Wicks Gene
Название: Stereochemical and Reactivity Studies of the [2 2], [2 4] and 1,3-dipolar Cycloadditions of Partially Fluorinated Allenes
ISBN: 0530006308 ISBN-13(EAN): 9780530006307
Издательство: Неизвестно
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Цена: 80930.00 T
Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: Abstract:

Cycloadditions involving fluoroallenes are extremely useful mechanistic probes. Due to the high reactivity of these allenes and the small size of their fluorine substituents, cycloadditions of fluoroallenes are free from many of the ambiguities surrounding analogous studies by previous workers.

Styrene and 1,1-difluoroallene, DFA, undergo clean reactions between 60o and 100oC to give good yields (approx. 60%) of two cylcloadducts: 2,2-difluoro-3-phenyl-1-methylenecyclobutane (major) and 3-phenyl-1-(difluoromethylene)cyclobutane (minor). Similar experiments comparing the reactions of p-nitro and p-methoxystyrene with the above results give relative reactivities of 2.1 and 1.3, respectively. The 2]2] cycloaddition of DFA with Z-β-deuteriostyrene gives the expected products in an 82:18 ratio with stereochemical ratios of 58:42 and 79:21, respectively, at 80oC. A mechanism involving two kinetically distinguishable diradicals is proposed to rationalize the results. The reaction of DFA with 1-cyanovinyl acetate, a "capto-dative" reagent is also studied and found to give results similar to the styrene reactions.

N-Methyl, N-phenyl, and N-(2-naphthyl)-C-phenylnitrones undergo regiospecific C2-C3 dipolar cycloadditions with monofluoroallene, MFA, in nearly quantitative yields at 25oC. The average stereochemical ratio for the two 4-substituted isoxazolidines produced is 84:16 2% with the product from syn addition of MFA in excess. The stereochemical assignments of the products are made with the aid of difference nuclear Overhauser effect (NOE) experiments and an X-ray crystal structure. Extensive solvent and kinetic studies show that these are well-behaved second-order kinetic processes consistent with previously well-studied 1,3-dipolar cycloadditions. The reaction of MFA with diazomethane-d2 strongly favors the product from the syn addition (88:12 ratio), also. Consideration of transition-state dipole-dipole interactions and solvation phenomena show that the factors affecting the stereochemical outcome of all these 1,3-dipolar cycloadditions are extremely subtle.

Finally, MFA undergoes Diels-Alder reactions with cyclopentadiene, butadiene, and furan to give a modest preference for the syn adduct (51:49, 59:41, and 63:37, respectively). The results are discussed in terms of a theoretical study done for MFA using INDO calculations.

Dissertation Discovery Company and University of Florida are dedicated to making scholarly works more discoverable and accessible throughout the world. This dissertation, "Stereochemical and Reactivity Studies of the 2 2], 2 4] and 1,3-dipolar Cycloadditions of Partially Fluorinated Allenes" by Gene Ellis Wicks, was obtained from University of Florida and is being sold with permission from the author. A digital copy of this work may also be found in the university's institutional repository, IR@UF. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation.

Автор: Sullivan, William G. Wicks, Elin M. Koelling, C. P
Название: Engineering economy, global edition
ISBN: 129226490X ISBN-13(EAN): 9781292264905
Издательство: Pearson Education
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Цена: 113290.00 T
Наличие на складе: Невозможна поставка.
Описание: Lexical Conflict combines theoretical and applied linguistic perspectives to explore the lexical richness of over 100 world languages. The text systematises cross-linguistic and cross-cultural differences, and then formulates strategies of lexicographic treatment across these differences, building a foundation for the establishment of similar solutions in other branches of applied linguistics.