In the last two decades, metal-organic frameworks (MOFs) have provoked considerable interest due to their potential applications in different fields such as catalysis, gas storage and sensing. The most important advantages of MOFs over other porous materials is the ability of tailoring their pore size, functionality and even the topology of the framework by rational selection of the molecular building blocks. Therefore, many chemists have tried to engineer the structure of MOFs to achieve specific functions.
Pillared metal organic frameworks are a class of MOFs composed of inorganic secondary building units (SBUs) and two sets of organic linkers, generally oxygen- and nitrogen-donor ligands. Typically, in the structure of pillared MOFs, the oxygen-donor struts link the metal clusters into a two-dimensional (2D) sheet and the N-donor struts pillar the sheets to generate a three-dimensional (3D) framework. Thus, the construction of MOFs by utilizing two sets of organic linkers could provide an extra possibility for further tuning of MOF's pore walls. A variety of functional groups including imine, amide and heterocycles were successfully incorporated into bidentate pillar ligand skeleton. Interestingly, by using pillaring linkers with different length, a wide diversity of metal-organic frameworks with tunable pore dimensions and topologies can be obtained. In this book, we introduce pillared metal organic frameworks with their properties and applications.
Автор: Schr?der Название: Functional Metal-Organic Frameworks: Gas Storage, Separation and Catalysis ISBN: 3642146120 ISBN-13(EAN): 9783642146121 Издательство: Springer Рейтинг: Цена: 304750.00 T Наличие на складе: Есть у поставщика Поставка под заказ. Описание: Cooper - Hydrogen, Methane and Carbon Dioxide Adsorption in Metal-Organic Framework MaterialsBy X. Schroder-Doping of Metal-Organic Frameworks with Functional Guest Molecules and NanoparticlesBy F. Fischer-Chiral Metal-Organic Porous Materials: Synthetic Strategies and Applications in ChiralSeparation and CatalysisBy K.
Автор: Horne Bradley Название: Organic Chemistry: An Introduction ISBN: 1682854752 ISBN-13(EAN): 9781682854754 Издательство: Неизвестно Цена: 164150.00 T Наличие на складе: Есть у поставщика Поставка под заказ. Описание: As a sub-field of chemistry, organic chemistry refers to the study and analysis of compounds, which contain atoms of carbon. It focuses on the study of the properties, structure and characteristics of these organic compounds. The most common compounds studied under this field are organometallic compounds, hydrocarbon compounds, metalloids, transition metals, etc. This book is a compilation of chapters that discuss the most vital concepts in the field of organic chemistry. It outlines the processes and applications of this field in detail. The topics covered in this extensive textbook deal with the core aspects of organic chemistry. It aims to serve as a resource guide for students and experts alike and contribute to the growth of the discipline.
Автор: Patrick, Graham Название: Organic Chemistry: A Very Short Introduction (Paperback) ISBN: 0198759770 ISBN-13(EAN): 9780198759775 Издательство: Oxford Academ Рейтинг: Цена: 10550.00 T Наличие на складе: Есть у поставщика Поставка под заказ. Описание: Organic chemistry concerns the properties and synthesis of carbon-based molecules. Carbon atoms can concatenate into long chains and cyclic compounds, bonding with a variety of other elements, so the possible structures are almost limitless. Graham Patrick explores the world of organic chemistry and its wide applications.
Автор: Martin Schr?der Название: Functional Metal-Organic Frameworks: Gas Storage, Separation and Catalysis ISBN: 3642264883 ISBN-13(EAN): 9783642264887 Издательство: Springer Рейтинг: Цена: 287330.00 T Наличие на складе: Есть у поставщика Поставка под заказ. Описание: Cooper - Hydrogen, Methane and Carbon Dioxide Adsorption in Metal-Organic Framework MaterialsBy X. Schroder-Doping of Metal-Organic Frameworks with Functional Guest Molecules and NanoparticlesBy F. Fischer-Chiral Metal-Organic Porous Materials: Synthetic Strategies and Applications in ChiralSeparation and CatalysisBy K.
Автор: Michele Aresta, Angela Dibenedetto, Franck Dumeignil Название: Biorefineries: An Introduction ISBN: 3110331535 ISBN-13(EAN): 9783110331530 Издательство: Walter de Gruyter Цена: 86720.00 T Наличие на складе: Есть у поставщика Поставка под заказ. Описание: Biorefineries compiles the basic science and technologies used to convert terrestrial and aquatic biomass into essential molecular compounds and polymeric materials. The book provides in depth insights into this fairly recent concept of industrial chemistry that aims to achieve optimal economic profits while minimizing the environmental impact. Chapters written by renowned experts cover, amongst others, the application of catalysis, downstream processing, biomass sourced olefins, lignin biorefinery techniques and biogas.The authors thoroughly examine and explain the value chain for biomass conversion into platform molecules and their transformation into final products. A comprehensive thematic overview on the topic giving beginners access to fundamental concepts is presented. Supplemented by numerous full color figures and tables, the contents impart knowledge about the involved techniques. Advanced students and experts in the field will find the summary of state-of-the-art research and current literature of valuable interest. Explores the enormous potential of biomass conversion as a future source for fuels and chemicals Focuses on both general scientific background and current innovations in the field of biorefinery Targets students and researchers in Chemistry, Chemical Engineering, Biotechnology, and Materials Science About the Editors Prof. Michele Aresta, Chair of the Scientific Committee of CIRCC in Italy and holds the IMM Chair at the Department of Chemical and Biomolecular Engineering at NUS, Singapore. He is author of over 200 papers and Author or Editor of nine books. Prof. Angela Dibenedetto, Associate Professor at the Department of Chemistry of the University of Bari (Italy) focused on carbon dioxide utilization by applying biorefinery concepts; and Director of the Interuniversity Consortium on Chemical Reactivity and Catalysis-CIRCC. Prof. Franck Dumeignil, Deputy Director of the CNRS joint Unit of Catalysis and Chemistry of Solid (UCCS) of Lille University (France); project coordinator of several projects on chemistry, including the EuroBioRef Project for designing next generation biorefineries.
Автор: Basudev Sahoo Название: Visible Light Photocatalyzed Redox-Neutral Organic Reactions and Synthesis of Novel Metal-Organic Frameworks ISBN: 3319483498 ISBN-13(EAN): 9783319483498 Издательство: Springer Рейтинг: Цена: 111790.00 T Наличие на складе: Есть у поставщика Поставка под заказ. Описание: This unique thesis discusses the development of conceptually novel and synthetically valuable methods that use visible light photocatalysis. Each chapter addresses a different topic in the emerging field of photocatalysis, which has become an indispensable tool for organic synthesis. Photocatalysis employs environmentally harmless and abundant visible light in the presence of a photosensitizer, and as such offers an attractive alternative to harmful UV light in photo-mediated reactions. This book introduces the novel concept of merging gold catalysis with visible light photocatalysis in a dual catalytic fashion, which demonstrates their compatibility with each other for first time and has inspired the development of various reactions. Moreover, a novel trifluoromethylation method, which combines radical addition chemistry with a polar rearrangement to synthesize valuable fluorinated compounds, is presented, since compounds featuring fluorinated functionality are the subject of increasing attention in pharmaceutical, agrochemical and material research. It also develops an external photocatalyst-free photochemical method for the synthesis of valuable indolizine heterocycles, where the product mediates its own formation. Lastly, it describes the synthesis and characterization of two novel highly porous metal-organic frameworks (MOFs). The comprehensive text is rounded out with illustrations and color figures.
Автор: William H. Brown, Thomas Poon Название: Introduction to Organic Chemistry, 6th Edi tion Global Edition ISBN: 1119382882 ISBN-13(EAN): 9781119382881 Издательство: Wiley Рейтинг: Цена: 53850.00 T Наличие на складе: Есть у поставщика Поставка под заказ. Описание: Introduction to Organic Chemistry, 6th Global Edition provides an introduction to organic chemistry for students who require the fundamentals of organic chemistry as a requirement for their major. It is most suited for a one semester organic chemistry course. In an attempt to highlight the relevance of the material to students, the authors place a strong emphasis on showing the interrelationship between organic chemistry and other areas of science, particularly the biological and health sciences.
The text illustrates the use of organic chemistry as a tool in these sciences; it also stresses the organic compounds, both natural and synthetic, that surround us in everyday life: in pharmaceuticals, plastics, fibers, agrochemicals, surface coatings, toiletry preparations and cosmetics, food additives, adhesives, and elastomers.
Автор: Starkey Название: Introduction to Strategies for Organic Synthesis, 2nd Edition ISBN: 1119347246 ISBN-13(EAN): 9781119347248 Издательство: Wiley Рейтинг: Цена: 60140.00 T Наличие на складе: Есть у поставщика Поставка под заказ. Описание:
Bridging the Gap Between Organic Chemistry Fundamentals and Advanced Synthesis Problems
Introduction to Strategies of Organic Synthesis bridges the knowledge gap between sophomore-level organic chemistry and senior-level or graduate-level synthesis to help students more easily adjust to a synthetic chemistry mindset. Beginning with a thorough review of reagents, functional groups, and their reactions, this book prepares students to progress into advanced synthetic strategies. Major reactions are presented from a mechanistic perspective and then again from a synthetic chemist's point of view to help students shift their thought patterns and teach them how to imagine the series of reactions needed to reach a desired target molecule.
Success in organic synthesis requires not only familiarity with common reagents and functional group interconversions, but also a deep understanding of functional group behavior and reactivity. This book provides clear explanations of such reactivities and explicitly teaches students how to make logical disconnections of a target molecule.
This new Second Edition of Introduction to Strategies for Organic Synthesis
Reviews fundamental organic chemistry concepts including functional group transformations, reagents, stereochemistry, and mechanisms
Explores advanced topics including protective groups, synthetic equivalents, and transition-metal mediated coupling reactions
Helps students envision forward reactions and backwards disconnections as a matter of routine
Gives students confidence in performing retrosynthetic analyses of target molecules Includes fully-worked examples, literature-based problems, and over 450 chapter problems with detailed solutions
Provides clear explanations in easy-to-follow, student-friendly language
Focuses on the strategies of organic synthesis rather than a catalogue of reactions and modern reagents
The prospect of organic synthesis can be daunting at the outset, but this book serves as a useful stepping stone to refresh existing knowledge of organic chemistry while introducing the general strategies of synthesis. Useful as both a textbook and a bench reference, this text provides value to graduate and advanced undergraduate students alike.
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