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Alkane C-H Activation by Single-Site Metal Catalysis, Pedro J. P?rez


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Автор: Pedro J. P?rez
Название:  Alkane C-H Activation by Single-Site Metal Catalysis
ISBN: 9789401781879
Издательство: Springer
Классификация:

ISBN-10: 9401781877
Обложка/Формат: Paperback
Страницы: 270
Вес: 0.40 кг.
Дата издания: 15.10.2014
Серия: Catalysis by Metal Complexes
Язык: English
Размер: 234 x 156 x 15
Основная тема: Chemistry
Ссылка на Издательство: Link
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Поставляется из: Германии
Описание: Over the past decade, much research effort has been devoted to the design and synthesis of new reagents and catalysts that can influence carbon-hydrogen bond activation, mainly because of the prospect that C H activation could enable the conversion of cheap and abundant alkanes into valuable functionalized organic compounds.

Novel Approaches for Single Molecule Activation and Detection

Автор: Fabio Benfenati; Enzo Di Fabrizio; Vincent Torre
Название: Novel Approaches for Single Molecule Activation and Detection
ISBN: 3662433664 ISBN-13(EAN): 9783662433669
Издательство: Springer
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Цена: 156720.00 T
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Описание: These devices are based on the developments of new photonic tools able to activate and stimulate single molecule machines. These technological innovations will provide a way to control activation of single light-sensitive molecules, allowing the investigation of molecular computation in a biological environment.

New Carbon–Carbon Coupling Reactions Based on Decarboxylation and Iron-Catalyzed C–H Activation

Автор: Shang
Название: New Carbon–Carbon Coupling Reactions Based on Decarboxylation and Iron-Catalyzed C–H Activation
ISBN: 9811031924 ISBN-13(EAN): 9789811031922
Издательство: Springer
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Цена: 93160.00 T
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Описание: This thesis presents the latest developments in new catalytic C–C bond formation methods using easily accessible carboxylate salts through catalytic decarboxylation with good atom economy, and employing the sustainable element iron as the catalyst to directly activate C–H bonds with high step efficiency. In this regard, it explores a mechanistic understanding of the newly discovered decarboxylative couplings and the catalytic reactivity of the iron catalyst with the help of density functional theory calculation. The thesis is divided into two parts, the first of which focuses on the development of a series of previously unexplored, inexpensive carboxylate salts as useful building blocks for the formation of various C–C bonds to access valuable chemicals. In turn, the second part is devoted to several new C–C bond formation methodologies using the most ubiquitous transition metal, iron, as a catalyst, and using the ubiquitous C–H bond as the coupling partner.


Catalytic Activation and Functionalisation of Light Alkanes

Автор: E.G. Derouane; Jerzy Haber; Francisco Lemos; Ferna
Название: Catalytic Activation and Functionalisation of Light Alkanes
ISBN: 0792349601 ISBN-13(EAN): 9780792349600
Издательство: Springer
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Цена: 287890.00 T
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Описание: Light alkanes tend to be resistant to many forms of activation. This book covers homogeneous, heterogeneous and biological catalysis and helps readers to gain an awareness of progress and ideas in research areas different from their own. It is intended for newcomers and senior researchers in the field of alkane activation.

Electrochemical Activation of Catalysis

Автор: Costas G. Vayenas; Symeon Bebelis; Costas Pliangos
Название: Electrochemical Activation of Catalysis
ISBN: 1475782349 ISBN-13(EAN): 9781475782349
Издательство: Springer
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Цена: 148020.00 T
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Описание: Whether electron transfer is complete in such a case, or whether the effect is on the desorption of radicals, the work function determines the strength of their bonding, and if one varies the work function by varying the electrode potential, one can vary the reaction rate at the interface.

Electrochemical Activation of Catalysis

Автор: Costas G. Vayenas; Symeon Bebelis; Costas Pliangos
Название: Electrochemical Activation of Catalysis
ISBN: 0306467194 ISBN-13(EAN): 9780306467196
Издательство: Springer
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Цена: 174150.00 T
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Описание: Describes the phenomenology, theory and potential applications of the phenomenon of electrochemical promotion. The origin of electrochemical promotion is discussed in light of a plethora of surface spectroscopic and electrochemical techniques. This work also compares electrochemical and classical promotion.

Novel Approaches for Single Molecule Activation and Detection

Автор: Fabio Benfenati; Enzo Di Fabrizio; Vincent Torre
Название: Novel Approaches for Single Molecule Activation and Detection
ISBN: 366252337X ISBN-13(EAN): 9783662523377
Издательство: Springer
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Цена: 130590.00 T
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Описание: These devices are based on the developments of new photonic tools able to activate and stimulate single molecule machines. These technological innovations will provide a way to control activation of single light-sensitive molecules, allowing the investigation of molecular computation in a biological environment.

Mechanistic Studies on Transition Metal-Catalyzed C–H Activation Reactions Using Combined Mass Spectrometry and Theoretical Methods

Автор: Gui-Juan Cheng
Название: Mechanistic Studies on Transition Metal-Catalyzed C–H Activation Reactions Using Combined Mass Spectrometry and Theoretical Methods
ISBN: 9811045208 ISBN-13(EAN): 9789811045202
Издательство: Springer
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Цена: 102480.00 T
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Описание: The reactions investigated include: (i) a nitrile-containing template-assisted meta-selective C-H activation, (ii) Pd/mono-N-protected amino acid (MPAA) catalyzed meta-selective C-H activation, (iii) Pd/MPAA catalyzed asymmetric C-H activation reactions, and (iv) Cu-catalyzed sp3 C-H cross-dehydrogenative-coupling reaction.

Catalytic Activation of Dioxygen by Metal Complexes

Автор: L?szl? I. Sim?ndi
Название: Catalytic Activation of Dioxygen by Metal Complexes
ISBN: 079231896X ISBN-13(EAN): 9780792318965
Издательство: Springer
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Цена: 256220.00 T
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Описание: The activation of dioxygen by metal ions has both synthetic potential and biological relevance. This book gives a survey of the catalyst systems based on metal complexes. It reviews the chemistry of transition metal dioxygen complexes, which are usually the active intermediates in the catalytic reactions discussed.

Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes

Автор: A.E. Shilov; Georgiy B. Shul`pin
Название: Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes
ISBN: 0792361016 ISBN-13(EAN): 9780792361015
Издательство: Springer
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Цена: 243800.00 T
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Описание: A monograph that covers the activation and various transformations of saturated hydrocarbons (alkanes) - reactions accompanied by the C-H and C-C bond cleavage. It covers the reactions of saturated hydrocarbons, and considers the activation of C-H bonds in arenes and olefins and acetylenes.

Activation of Saturated Hydrocarbons by Transition Metal Complexes

Автор: A.E. Shilov
Название: Activation of Saturated Hydrocarbons by Transition Metal Complexes
ISBN: 9027716285 ISBN-13(EAN): 9789027716286
Издательство: Springer
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Цена: 158380.00 T
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Catalytic Activation of Dioxygen by Metal Complexes

Автор: L?szl? I. Sim?ndi
Название: Catalytic Activation of Dioxygen by Metal Complexes
ISBN: 9401052654 ISBN-13(EAN): 9789401052658
Издательство: Springer
Рейтинг:
Цена: 186330.00 T
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Описание: The activation of dioxygen by metal ions has both synthetic potential and biological relevance. An introductonary chapter reviews the chemistry of transition metal dioxygen complexes, which are usually the active intermediates in the catalytic reactions discussed.

C-H Activation

Автор: Jin-Quan Yu; Zhangjie Shi
Название: C-H Activation
ISBN: 3642263593 ISBN-13(EAN): 9783642263590
Издательство: Springer
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Цена: 330870.00 T
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Описание: Synthesis in the Key of Catellani: Norbornene-Mediated ortho C-H Functionalization.- Mechanistic Considerations in the Development and Use of Azine, Diazine and Azole N-Oxides in Palladium-Catalyzed Direct Arylation.- Palladium and Copper Catalysis in Regioselective, Intermolecular Coupling of C-H and C-Hal Bonds.- Pd-Catalyzed C-H Bond Functionalization on the Indole and Pyrrole Nucleus.- Remote C-H Activation via Through-Space Palladium and Rhodium Migrations.- Palladium-Catalyzed Aryl-Aryl Bond Formation Through Double C-H Activation.- Palladium-Catalyzed Allylic C-H Bond Functionalization of Olefins.- Ruthenium-Catalyzed Direct Arylations Through C-H Bond Cleavages.- Rhodium-Catalyzed C-H Bond Arylation of Arenes.- Cross-Dehydrogenative Coupling Reactions of sp3-Hybridized C-H Bonds.- Functionalization of Carbon-Hydrogen Bonds Through Transition Metal Carbenoid Insertion.- Metal-Catalyzed Oxidations of C-H to C-N Bonds.


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